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31.
32.
Rados?aw Przenios?o Wouter van BeekIzabela Sosnowska 《Solid State Communications》2003,126(9):485-488
The structural phase transition in annealed CaMn7O12 has been investigated by using high resolution synchrotron radiation powder diffraction. There is a phase coexistence phenomenon: two different crystallographic phases coexist in the material between 410 and 458 K. The first one is trigonal and it has a charge ordering (CO) of the Mn3+ and Mn4+ ions, while the second one is cubic and charge delocalized (CD). The volume fraction of the CD phase increases with temperature from 22% at 418 K up to 100% at 468 K. Both phases have domains of at least 150 nm at each temperature. The annealing of CaMn7O12 relaxed a part of the strains in the lattice, but did not influence the phase coexistence phenomenon. 相似文献
33.
Herrebout WA Melikova SM Delanoye SN Rutkowski KS Shchepkin DN van der Veken BJ 《The journal of physical chemistry. A》2005,109(13):3038-3044
Mid-infrared spectra of mixed solutions in liquid xenon containing fluoroform and either ammonia or pyridine have been investigated at temperatures between 173 and 213 K. For both Lewis bases, a new band is found in the CH stretching region at a frequency approximately 5 cm(-1) higher than that of monomer fluoroform, which is assigned to a complex between fluoroform and the Lewis base. A detailed analysis of the nu1/2nu(4) Fermi resonance in the proton donor shows that the blue shifts observed for the complexes are not caused by a strengthening of the CH bond during the complexation, but are due to the changes in the Fermi resonance interactions. Information on the nu1/2nu(4) Fermi resonance was also obtained for the complexes of fluoroform with dimethyl ether and trimethyl amine. 相似文献
34.
This paper exemplifies discrete analogs obtained by transformation of the continuum equations governing porous media flow to a system of algebraic equations. To give insight in the underlying physics, the numerical examples are worked out algebraically. The volume-centered approximation turns out to be a reasonable simplification of the algebraically exact face-centered method. 相似文献
35.
Wouter Caarls M. Soledad Celej Alexander P. Demchenko Thomas M. Jovin 《Journal of fluorescence》2010,20(1):181-190
Fluorescence probes with multiparametric response based on the relative variation in the intensities of several emission bands
are of great general utility. An accurate interpretation of the system requires the determination of the number, positions
and intensities of the spectral components. We have developed a new algorithm for spectral deconvolution that is applicable
to fluorescence probes exhibiting a two-state ground-state equilibrium and a two-state excited-state reaction. Three distinct
fluorescence emission bands are resolved, with a distribution of intensities that is excitation-wavelength-dependent. The
deconvolution of the spectrum into individual components is based on their representation as asymmetric Siano-Metzler log-normal
functions. The application of the algorithm to the solvation response of a 3-hydroxychromone (3HC) derivative that exhibits
an H-bonding-dependent excited-state intramolecular proton transfer (ESIPT) reaction allowed the separation of the spectral
signatures characteristic of polarity and hydrogen bonding. This example demonstrates the ability of the method to characterize
two potentially uncorrelated parameters characterizing dye environment and interactions. 相似文献
36.
Bertine L. Stehouwer Dennis W.J. KlompMies A. Korteweg Helena M. VerkooijenPeter R. Luijten Willem P.Th.M. MaliMaurice A.A.J. van den Bosch Wouter B. Veldhuis 《Magnetic resonance imaging》2013
Purpose
Here we describe our first experience with contrast-enhanced (CE) MRI of breast cancer at 7 tesla (T), compared to 3 T and histopathology.Materials and Methods
A 52 year old female patient with a mammographically suspicious breast mass (BI-RADS V) underwent 7 T CE-MRI. Results were described according to the BI-RADS-MRI criteria and compared to 3 T and histopathology.Results
After contrast administration, a homogeneously enhancing, irregular spiculated mass was depicted at both 3 T and 7 T; sizes were identical. The most malignant kinetic curve was characterized by a rapid initial rise followed by a wash-out pattern in the delayed phase, i.e. a type 3 curve, at both field strengths. Even though T1-effects of contrast agents are suggested to be reduced at higher fields, quantification of contrast enhancement-to-noise ratio showed a ratio of 4.6 at 7 T and 2.8 at 3 T when comparing contrast-to-noise of the mass before and after contrast administration. Both examinations, using a single dose of gadolinium-based contrast agent, achieved good image quality. Final histopathological evaluation showed an invasive ductulolobular carcinoma with an intraductal component.Conclusion
This initial experience suggests that clinical contrast-enhanced 7 T MRI of the breast is technically feasible and may allow BI-RADS-conform analysis. 相似文献37.
Let $\mathbb{F}_{q}$ be a finite field, and let b and N be integers. We prove explicit estimates for the probability that the number of rational points on a randomly chosen elliptic curve E over $\mathbb{F}_{q}$ equals b modulo N. The underlying tool is an equidistribution result on the action of Frobenius on the N-torsion subgroup of E. Our results subsume and extend previous work by Achter and Gekeler. 相似文献
38.
Raoul Walther Anna K. Winther Anne Sofie Fruergaard Wouter vandenAkker Lise Srensen Signe Maria Nielsen Morten T. JarlstadOlesen Yitao Dai Henrik S. Jeppesen Paolo Lamagni Aleksandr Savateev Sren Lykke Pedersen Camilla Kaas Frich Ccile Vigier‐Carrire Nina Lock Mandeep Singh Vipul Bansal Rikke L. Meyer Alexander N. Zelikin 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(1):284-288
Nanozymes, nanoparticles that mimic the natural activity of enzymes, are intriguing academically and are important in the context of the Origin of Life. However, current nanozymes offer mimicry of a narrow range of mammalian enzymes, near‐exclusively performing redox reactions. We present an unexpected discovery of non‐proteinaceous enzymes based on metals, metal oxides, 1D/2D‐materials, and non‐metallic nanomaterials. The specific novelty of these findings lies in the identification of nanozymes with apparent mimicry of diverse mammalian enzymes, including unique pan‐glycosidases. Further novelty lies in the identification of the substrate scope for the lead candidates, specifically in the context of bioconversion of glucuronides, that is, human metabolites and privileged prodrugs in the field of enzyme‐prodrug therapies. Lastly, nanozymes are employed for conversion of glucuronide prodrugs into marketed anti‐inflammatory and antibacterial agents, as well as “nanozyme prodrug therapy” to mediate antibacterial measures. 相似文献
39.
A Lagrangian study of two-dimensional turbulence for two different geometries, a periodic and a confined circular geometry, is presented to investigate the influence of solid boundaries on the Lagrangian dynamics. It is found that the Lagrangian acceleration is even more intermittent in the confined domain than in the periodic domain. The flatness of the Lagrangian acceleration as a function of the radius shows that the influence of the wall on the Lagrangian dynamics becomes negligible in the center of the domain, and it also reveals that the wall is responsible for the increased intermittency. The transition in the Lagrangian statistics between this region, not directly influenced by the walls, and a critical radius which defines a Lagrangian boundary layer is shown to be very sharp with a sudden increase of the acceleration flatness from about 5 to about 20. 相似文献
40.